| Keith Lamont Scott (L) and Officer Brently Vinson (R) |
The moment North Carolina police
shot a black man was captured on video by his wife, who can be heard
pleading with officers: "Don't shoot him!"
Officers can be heard urging him to "drop the gun" but his wife is heard telling them he is unarmed.
On Friday evening, a few hundred protestors took to the streets, but the demonstrations was smaller than on the previous three nights.
They chanted "No justice, no peace" and "Release the video" - a call for the police to release their dash-cam and body-cam images of the incident.
The state governor has declared a state of emergency in the city, and a midnight curfew has been imposed for a second night running, after rioters looted businesses and threw objects at police on Tuesday and Wednesday nights.
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Charlotte city leaders have been under mounting pressure to release their footage of this week's shooting.
Democratic presidential candidate Hillary Clinton joined the chorus, adding: "We must ensure justice and work to bridge divides."
Mrs Clinton's campaign team had said she would visit Charlotte on Sunday, but later announced the visit was being postponed until the following Sunday after discussion with community leaders "as to not impact the city's resources".
In the clip, an officer is heard shouting: "Hands up!"
Mrs Scott cries: "Don't shoot him. Don't shoot him. He has no weapon. He has no weapon. Don't shoot him."